Abstract:
Based on ground meteorological and environmental monitoring station data, O3 meteorological condition evaluation index, O3 Source apportionment products, OMI remote sensing data, GDAS and other data, combined with HYSPLIT model and other methods, the spatiotemporal variation characteristics of O3 pollution in Shaanxi from May to October 2019 to 2023 were analyzed. The impact of meteorological conditions on O3 concentration changes was quantitatively evaluated, and the local and transmission contributions of O3 pollution, as well as the contributions of different precursors, were quantitatively separated. Finally, the pollution transmission path was explored. The results show that in the warm season of 2022, O3 pollution in Shaanxi is the heaviest, and in 2020, the pollution is the lightest. The O3 concentration shows a typical unimodal monthly and daily variation, with a monthly peak occurring in June, a daily maximum occurring from 15:00 to 16:00, and a minimum occurring at 7:00. The O3 concentration on non working days is lower than that on working days. The O3 pollution in Guanzhong is the heaviest, and the pollution is mainly concentrated in the inner layer of the trumpet mouth terrain in the Guanzhong Plain, with the lightest in southern Shaanxi. From May to October 2022, the daily average total radiation exposure in Shaanxi is the highest (17.28MJ/m2), the daily maximum temperature is the highest (27.7℃), the number of precipitation days is the lowest (56d), and the sunshine duration is relatively long (6.4h). The O3 comprehensive meteorological conditions are the worst, which is the main reason for the heaviest O3 pollution in Shaanxi in 2022. From May to October 2022, the O3 concentration in Shaanxi increases by 8.1% compared to the same period last year, and meteorological conditions can increase it by 7.7% compared to the same period last year. If the emission source remains unchanged, the O3 concentration in Shaanxi Province from May to October 2020 should have increased by 4.4% compared to the same period in 2019, but the actual O3 concentration has decreased by 5.3%, which fully reflects the positive effects of regional air pollution control. The O3 comprehensive meteorological conditions in northern Shaanxi are the worst, but the O3 concentration in Guanzhong is the highest, which is mainly related to the high emissions of O3 precursors and regional transportation in Guanzhong. From May to October 2023, the concentration of O3 in Shaanxi Province is mainly affected by precursor NOx, and the contribution of external transport (45%) is greater than that of local transport (17%). The main transport pathway is in the southeast, with Henan and Hubei provinces having the greatest impact on Shaanxi transport, contributing 6% and 4% respectively.